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 During the Asian summer monsoon period, total ozone over the Tibetan Plateau is much lower than that over the surrounding areas when compared at the same latitudes. This phenomenon called the “ozone valley” was investigated continuously with the use of ozonesondes and Earth Probe/Total Ozone Mapping Spectrometer (EP/TOMS). These measurements reveal that although relatively low ozone mixing ratios extend from the troposphere to the lower stratosphere, those near the tropopause (between about 150 and 70 hPa) largely contribute to lower total ozone over the Tibetan Plateau. Temperatures near the tropopause appear to be correlated with the observed ozone changes. Meteorological analyses show that this phenomenon is accompanied by the upper level monsoon anticyclone, which is characterized by deep convection over South Asia. These results suggest that lower ozone mixing ratios and colder temperatures near the tropopause are primarily due to convection, which is linked to the Asian summer monsoon.
 Total column ozone over mountainous areas is relatively low as compared to non-mountainous areas at the same latitudes. The Tibetan Plateau has an average elevation of >4000 meters and occupies an area of about 2.5 million square kilometers in South Asia. Hence one would expect low total ozone over the Tibetan Plateau to be associated with missing the integrated ozone columns from the mountain to non-mountain ground surfaces. However, it is evident that the negative deviations from the zonal mean total ozone are much larger in summer than in winter, indicating summertime decreases in total ozone over the Tibetan Plateau [Zhou and Luo, 1994; Zou, 1996]. This regional phenomenon found in summer is dubbed the “ozone valley”. The ozone valley is small in scale as compared to the Antarctic “ozone hole”, but major in radiative effect; because the ozone valley is formed in summertime when the Tibetan Plateau and its residents are exposed to extra strong sunlight.
 The mechanisms responsible for the low total ozone have been discussed for decades. In particular, the possibility of linkages between ozone and the Asian summer monsoon circulation is of interest. During summer, the elevated surface heating and rising air over the Tibetan Plateau lead to anticyclonic circulation and divergence in the upper troposphere and lower stratosphere [Yanai et al., 1992]. The upper level monsoon anticyclone (i.e., Tibetan anticyclone) exhibits intraseasonal variability and travels to and fro between two preferred regions, namely the Tibetan Plateau and the Iranian Plateau [Zhang et al., 2002]. Recent satellite measurements and model studies have focused on the importance of the Tibetan anticyclone and its coupling to deep convection that has the potential to transport ozone-poor air from the boundary layer into the upper troposphere and also lower stratosphere [Gettelman et al., 2004; Randel and Park, 2006; Park et al., 2007].
 The height dependence of the ozone changes is important for understanding mechanisms responsible for the occurrence of the ozone valley over the Tibetan Plateau; however, few in-situ measurements have documented it. In this study, we present total ozone and ozonesonde measurements of the ozone valley over the Tibetan Plateau in the summer of 1999. We show that minima in total ozone are linked to the development of the Tibetan anticyclone, and relatively low ozone mixing ratios extend to the lowermost stratosphere as well as troposphere. These results raise the possibility that deep convection could primarily affect ozone mixing ratios and hence temperatures near the tropopause.
2. Data and Analyses
 Time series of total column ozone are obtained from the Earth Probe/Total Ozone Mapping Spectrometer (EP/TOMS) version 8 operated by the National Aeronautics Space Administration/Goddard Space Flight Center (NASA/GSFC). The EP/TOMS dataset uses a horizontal resolution of 1° latitude × 1.25° longitude. The unit for total ozone is Dobson Unit (DU; 1 DU is defined as 0.01 mm thickness at 1°C and 1 atmospheric pressure). More information is available at http://toms.gsfc.nasa.gov/eptoms/ep_v8.html.
 In addition, a detailed analysis of the vertical structure of the ozone changes is performed by using balloon-borne measurements in the summer of 1999 at Lhasa (29.7°N, 91.1°E, 3650 meters above sea level), located in the southern part of the Tibetan Plateau. The ozone and temperature profiles were measured with an electrochemical concentration cell (ECC) ozonesonde and radiosonde. Here we use the results for 18–25 August 1999 (no available data on 20 August 1999). For the purpose of comparison with non-mountainous areas at similar latitudes, we refer to the monthly mean ozone and temperature profiles derived from systematic balloon-borne measurements at Kagoshima (31.6°N, 130.5°E, 31 meters above sea level), located in the southwestern part of Japan. Note that Japanese KC96 ozonesondes are used for ozone measurements at Kagoshima. According to Deshler et al. , the KC96 ozonesondes tend to underestimate ozone while the ECC ozonesondes overestimate. The precisions are about 5–15% at pressures >30 hPa.
 This study also uses horizontal wind fields retrieved from the National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) daily reanalysis data [Kalnay et al., 1996], available with a horizontal resolution of 2.5° latitude × 2.5° longitude and 17 pressure levels from 1000 to 10 hPa. The NCEP/NCAR reanalysis data is used to investigate the development and motion of the anticyclone in the upper troposphere and lower stratosphere. In addition, the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model (http://www.arl.noaa.gov/ready/hysplit4.html) is used to quantify the backward trajectories for the observation period.
3. Specification of Low Ozone Event
Figures 1a and 1b illustrate the geographical distributions of total ozone averaged for 18–22 August and for 23–27 August 1999, respectively. Figure 1a shows observable minima in total ozone over the Tibetan Plateau at 80°–100°E, indicating the occurrence of the ozone valley. Horizontal wind fields at 100 hPa (near-tropopause) are also plotted in Figures 1a and 1b. The meteorological analysis indicates that a synoptic-scale anticyclone was initially located over the Tibetan Plateau and coherent with minimum total ozone there. After that, the anticyclone started to move to the westward and then developed over the Iranian Plateau at 50°–70°E (Figure 1b). The changes in total ozone were linked to the movement of the anticyclone. Following the movement, total ozone in the vicinity of the Tibetan Plateau showed an increase and that of the Iranian Plateau exhibited a decrease.
Figure 2 show the vertical profiles of ozone mixing ratios at Lhasa during 18–25 August 1999, along with the monthly mean profiles of ozone mixing ratios at Kagoshima. There are some differences in the details of the shapes of these profiles. The balloon flights on 18–22 August 1999 were conducted within the Tibetan anticyclone. In these cases, there were little differences in tropospheric ozone mixing ratios between Lhasa and Kagoshima (note that Kagoshima is surrounded by sea and therefore frequently influenced by ozone-poor air). More importantly, relatively low ozone mixing ratios over Lhasa extended over broad layers ranging approximately to 70 hPa.
 The Tibetan anticyclone occurs primarily as a response to diabatic heating associated with deep convection over South Asia during summer [Yanai et al., 1992]. In cases where the anticyclonic circulation was formed over the Tibetan Plateau, temperatures from the ground surface to about 150 hPa over Lhasa was always higher than those over Kagoshima (Figure 2), suggesting an increase in diabatic heating and enhanced convection over the Plateau. This tropospheric warming leads to the reversal of meridional temperature gradient on the south of the Plateau [Yanai et al., 1992]. As a result, tropospheric ozone abundances over Lhasa during the low ozone event could be the result of the arrival of air masses transporting ozone-poor air from the Bay of Bengal and the Arabian Sea (see backward trajectories starting on 21–22 August 1999 in Figure 3). Also, given the occurrence of the anticyclone during the low ozone event, it is assumed that relatively low ozone mixing ratios near the tropopause are caused by the upward transport of ozone-poor air in deep convective systems.
 After 24 August 1999, the Tibetan Plateau was located at the eastern edge of the anticyclone and thus it is expected that convectively suppressed conditions prevailed over Lhasa. During this period, relatively high ozone mixing ratios were found from the ground surface to about 250 hPa (Figure 2). The air mass trajectories changed to pass over inland China (see backward trajectories staring on 24–25 August 1999 in Figure 3), indicating that the tropospheric ozone-rich air originated from continental sources. Ozonesonde measurements at Xining (36.4°N, 101.5°E, 2296 meters above sea level), located in the northeastern part of the Tibetan Plateau, show tropospheric ozone mixing ratios of >60 ppbv under normal summertime conditions [Zheng et al., 2004]. Thus, the relatively high ozone mixing ratios measured at Lhasa on 24–25 August 1999 are similar to those at Xining. In addition, the 25 August flight showed ozone recovery in the lowermost stratosphere, and as a consequence, negative ozone anomalies near the tropopause extended only to about 90 hPa. The 18 September flight that was conducted at the eastern edge of the anticyclone also indicated ozone recovery probably resulting from convectively suppressed conditions over the Plateau.
Figure 4a shows the integrated column ozone between 600 and 70 hPa based on ozonesonde measurements at Lhasa during 18–25 August 1999. Figure 4a also includes time series of the EP/TOMS total ozone over Lhasa in August 1999. These data show that the total ozone over Lhasa was largely influenced by ozone variations between 600 and 70 hPa. We further divide the integrated column ozone into three altitudes and examine the local ozone anomalies (deviations from the monthly mean ozone at Kagoshima). The results shown in Figures 4b, 4c, and 4d indicate the ozone valley to be a localized phenomenon that extends from about 150 to 70 hPa.
4. Temperature Changes Near the Tropopause
 The vertical profiles of temperatures at Lhasa during the observation period in this study are shown in Figure 2, together with the monthly mean data at Kagoshima. The local temperature anomalies (deviations from the monthly mean temperatures at Kagoshima) appeared most frequently over narrow layers near the tropopause between about 130 and 70 hPa. When the anticyclone developed over the Tibetan Plateau, cold temperature anomalies of about 5–10 K occurred near the tropopause. On the other hand, when the anticyclone shifted to the west, the anomalies were small. Thus, the temperature changes show patterns very similar to the observed ozone changes near the tropopause. Also, as shown in Figure 5, it seems likely that the temperatures vary with changes in the ozone mixing ratios.
5. Summary and Discussion
 Synoptic analyses of total column ozone and meteorological conditions have demonstrated that the occurrence of the ozone valley over the Tibetan Plateau is closely linked to the anticyclone in the upper troposphere and lower stratosphere (Figure 1). In addition, ozonesonde measurements at Lhasa have provided new information relevant to the vertical structure of the ozone valley. The vertical profiles of ozone mixing ratios within the Tibetan anticyclone indicate relatively low ozone mixing ratios extending to 70 hPa (Figure 2), suggesting that the anticyclone and its coupling to deep convection influences lower stratospheric as well as tropospheric ozone abundances over the Tibetan Plateau. The negative ozone anomalies near the tropopause between about 150 and 70 hPa largely contribute to a reduction in total ozone over the Tibetan Plateau (Figure 4).
 The relatively low ozone near the tropopause is primarily attributed to the upward transport of ozone-poor air in deep convective systems. Other satellite and model studies have also suggested minima in ozone mixing ratios within the monsoon anticyclone [Gettelman et al., 2004; Randel and Park, 2006; Park et al., 2007], which they attribute to seasonal changes in dynamics in the monsoon region. On the other hand, it has been reported that there are relatively high values of water vapor [Gettelman et al., 2004; Fu et al., 2006; Randel and Park, 2006; Park et al., 2004, 2007], methane, and NOx (=NO + NO2) [Park et al., 2004] near the summertime tropopause. The occurrence of cirrus clouds has also been observed [Fu et al., 2006; Tobo et al., 2007]. Other processes related to these species may have an affect on ozone abundances in the upper troposphere and lower stratosphere, and thus further investigations are needed to account for these sensitivities.
 The present results have indicated that temperatures near the tropopause are strongly correlated with the observed ozone changes (Figure 5). It is likely that cold temperature anomalies within the anticyclone at 100 hPa are primarily a dynamical response to enhanced convection [Park et al., 2007]. Although it is expected that the ozone changes have relatively a small effect on the energy budget of the tropopause, the reduction in ozone mixing ratios near the tropopause may reduce the radiative heating rate. Thus, comprehensive model studies as well as measurements of ozone and other greenhouse gases are needed to explain the mechanisms for the coupled temperature-ozone changes.
 We thank D. J. SuoLang and the staff members of the Meteorological Bureau of Tibet Autonomous Region for their technical supports in the fieldwork. We also thank the Japan Meteorological Agency for providing sonde data at Kagoshima and Katsuya Yamashita of the Meteorological Research Institute for his helpful support necessary for extensive discussions. This research was funded by the Japan Ministry of Education, Culture, Sports, Science and Technology (PI: Yasunobu Iwasaka, 10144104 and 10041115), National Natural Science Foundation of China (PI: Guangyu Shi, 49775275), and 21st -Century COE program of Kanazawa University (PI: Kazuichi Hayakawa).