Cold decade (AD 1810–1819) caused by Tambora (1815) and another (1809) stratospheric volcanic eruption

Authors


Abstract

[1] Climate records indicate that the decade of AD 1810–1819 including “the year without a summer” (1816) is probably the coldest during the past 500 years or longer, and the cause of the climatic extreme has been attributed primarily to the 1815 cataclysmic Tambora eruption in Indonesia. But the cold temperatures in the early part of the decade and the timing of the Tambora eruption call into question the real climatic impact of volcanic eruptions. Here we present new evidence, based on sulfur isotope anomaly (Δ33S), a unique indicator of volcanic sulfuric acid produced in the stratosphere and preserved in polar snow, and on the precise timing of the volcanic deposition in both polar regions, that another large eruption in 1809 of a volcano is also stratospheric and occurred in the tropics. The Tambora eruption and the undocumented 1809 eruption are together responsible for the unusually cold decade.

1. Introduction

[2] Major explosive volcanic eruptions emit into the atmosphere large amounts of ash and gases, often with immediate and destructive consequences for humans [Stothers, 1984]. Volcanic sulfur compounds (mainly SO2) are quickly oxidized to sulfuric acid forming sulfate aerosols that linger in the atmosphere for months to a few years. Large eruptions can impact climate [Robock, 2000], via radiative effects of the volcanic aerosols. Extraordinarily large eruptions injecting massive amounts of SO2 directly into the stratosphere can cause significant tropospheric and surface cooling [Robock, 2000]. Such eruptions in the tropics are capable of global impact, for their aerosols are distributed to both Northern and Southern Hemispheres. The global cooling effect of stratospheric volcanic aerosols provides the physical basis for the geoengineering proposition to counteract the human-enhanced greenhouse warming by injecting SO2 into the stratosphere [Crutzen, 2006; Wigley, 2006].

[3] Perhaps the best known historical example of the climatic impact of volcanic eruptions is “the year without a summer” (1816) following the great AD 1815 Tambora eruption [Stothers, 1984] on the Indonesian island of Sumbawa (8.25°S, 118.00°E). In fact, the period of 1810–1819 appears as the coldest decade over at least the past 500 years in many detailed climate records for the Northern Hemisphere and the tropics [Briffa et al., 1998; D'Arrigo et al., 2009; Jones et al., 1995]. The records show that not only were the post-Tambora years in the decade exceptionally cold, the pre-Tambora years, 1810 and 1811 in particular, also experienced significantly below-average temperatures. This raises a number of questions: How much of the cooling during this period was caused by Tambora and how much was due to other factors? Could the effect of aerosols on atmospheric energy budget be significantly overestimated [Myhre, 2009]? However, an important premise of these questions was that only one large, climate-impacting eruption (Tambora) occurred during the decade. If another large stratospheric eruption occurred shortly before 1815, the combined impact of Tambora and the other eruption could have been responsible for the unusually cold decade. No eruption of the Tambora magnitude is found during the period of 1800–1814 in the records of volcanic eruptions that are based on eyewitness accounts [Simkin and Siebert, 1994], indirect observations of atmospheric effects [Lamb, 1970], and limited volcanological data [Newhall and Self, 1982]. However, these observation-based records are often incomplete, due to lack of systematic reporting and documentation prior to the twentieth century [Simkin and Siebert, 1994; Stothers and Rampino, 1983].

[4] Polar ice cores provide proxy records of explosive global volcanism over many millennia [Castellano et al., 2005; Cole-Dai et al., 2000; Hammer et al., 1997; Zielinski et al., 1994]. These records are based on the measurement of volcanic-derived sulfuric acid, pioneered by C.U. Hammer and colleagues [Hammer, 1977; Hammer et al., 1980], and have distinct advantages over the observation-based records such as global and continuous coverage of extended time periods [Gao et al., 2008]. Volcanic sulfate was found in the 1809–1811 snow layers of Greenland as well as Antarctica ice cores [e.g., Cole-Dai et al., 1997, 2000; Dai et al., 1991; Mosley-Thompson et al., 2003; Palmer et al., 2001], and was considered as evidence of a large eruption in the tropics that distributed volcanic aerosols to both hemispheres. However, evidence from tephra (fine volcanic ash) in ice cores [Kurbatov et al., 2006; Yalcin et al., 2006] suggests that the sulfuric acid deposits on the Greenland and Antarctica ice sheets may have resulted from small or moderate eruptions that occurred contemporaneously in the high latitudes of both hemispheres. Here we present more specific and compelling evidence than the bi-polar sulfuric acid deposition in 1810–1811, in the form of unique isotopic composition of the volcanic sulfate in ice cores and of the precise timing of the volcanic deposition in the polar regions, to confirm a stratospheric eruption in 1809.

2. Data and Methods

2.1. Ice Cores

2.1.1. Greenland

[5] Four ice cores were drilled in 2007 in a small area (approximately 100 m2) at Summit (72.5°N, 38.5°W), Greenland. Core length varied from 75 meters to 200 meters, encompassing approximately 250 to 900 years, respectively. One core was analyzed continuously for concentrations of major ionic chemical impurities (including Na+, SO42−, Ca2+ and NO3) with the technique of continuous flow analysis with ion chromatography, or CFA-IC [Cole-Dai et al., 2006].

2.1.2. Antarctica

[6] Several ice cores from Dome C and South Pole, Antarctica used in this work have been described previously [Baroni et al., 2008; Budner and Cole-Dai, 2003]. The 2000/2001 South Pole cores were discretely and continuously sampled and analyzed with ion chromatography [Budner and Cole-Dai, 2003]. New for this work are two ice cores from WAIS Divide (79.5°S, 112.0°W), West Antarctica, obtained as part of the West Antarctica Ice Sheet (WAIS) Divide Ice Core Project. The 130-m WDC05Q core was drilled in 2005/2006, and the 2006/2007 WDC06A core is the top 114 m of the anticipated WAIS Divide deep core (∼3500 m). Both were analyzed continuously with CFA-IC for major ionic chemicals.

[7] All ice cores are dated with high accuracy and precision using the technique of counting annual cycles of ionic concentrations. Details of the dating procedures are included in the auxiliary material.

2.2. Volcanic Sulfate and Isotope Analysis

[8] Prominent volcanic events including Tambora and the 1809 eruptions were identified in ice cores by the elevated sulfate concentrations and the years when the elevated concentrations appear [e.g., Cole-Dai et al., 1997]. Depth intervals of the ice cores containing the sulfate of a volcanic event or of the non-volcanic background were decontaminated and melted, and the sulfate was extracted from the meltwater and purified as sulfuric acid using procedures described previously [Savarino et al., 2003a; Baroni et al., 2008]. The sulfuric acid was subsequently converted, through a series of chemical reactions, to SF6 gas, which was analyzed for sulfur isotope composition using isotope ratio mass spectrometry and established procedures [Rai and Thiemens, 2007; Savarino et al., 2001].

3. Results and Discussion

[9] Ice core records have uncovered past eruptions that left no eyewitness reports or contemporary observational documentation and therefore do not appear in the observation-based records. The missing may be major eruptions that have certainly impacted climate. For example, the AD 1452 or 1453 stratospheric eruption of the Kuwae volcano in the equatorial Pacific (16.8°S, 168.5°E), one of the most explosive eruptions in the last millennium in terms of atmospheric aerosol mass loading, has been found only in polar ice cores [Gao et al., 2006]. With regard to the early nineteenth century, an initial study [Dai et al., 1991] found high concentrations of sulfuric acid in the 1810–1811 snow layers in a few ice cores from Greenland and Antarctica and suggested that a stratospheric eruption occurred around the year of 1809, six years before the Tambora eruption. The volcanic fallout in both polar regions indicated the volcano was in the tropics, for only large eruptions in the tropics can deposit volcanic sulfuric acid in both polar regions. Results of subsequent studies [Cole-Dai et al., 1997, 2000; Mosley-Thompson et al., 2003; Palmer et al., 2001] confirm the presence of volcanic sulfuric acid in the 1810–1811 snow layers across Greenland and Antarctica.

[10] However, small or moderate eruptions emitting only tropospheric SO2 occur frequently, with no significant large-scale climatic impact [Robock, 2000; Simkin and Siebert, 1994]. Tropospheric eruptions in the high and mid-latitudes of Northern or Southern Hemisphere can also deposit volcanic sulfuric acid on the polar ice sheet of the respective hemisphere. Consequently, simultaneous sulfuric acid signals in bi-polar ice core records may be from coincidental tropospheric eruptions of volcanoes in the high/mid-latitudes of both hemispheres, and such signals alone are insufficient to confirm a past stratospheric eruption by a volcano in the tropics. A recent study [Yalcin et al., 2006] found tephra in the 1809 snow layer in an Arctic (Yukon Territory, Canada) ice core with chemical composition suggesting that a small or moderate volcanic eruption occurred that year in the high northern latitudes. The chemical composition of tephra in the 1809–1810 layer of a Siple Dome, West Antarctica ice core is reported [Kurbatov et al., 2006] to be consistent with that of ash from Antarctic volcanoes. These reports suggest that two contemporaneous but separate small or moderate eruptions, one in the high latitudes of the Northern Hemisphere and another in Antarctica, could be the sources of the volcanic sulfuric acid found in Greenland and Antarctica ice cores, respectively. This suggestion implies no large-scale climatic impact by volcanic eruption in the years immediately preceding the 1815 Tambora eruption, for only stratospheric eruptions in the tropics can cause significant global cooling [Robock, 2000].

[11] Volcanic emissions also impact atmospheric composition and chemistry. Sulfur dioxide in the stratosphere undergoes oxidation to H2SO4 with reaction pathways different from those in the troposphere [Baroni et al., 2007, 2008; Savarino et al., 2003a, 2003b]. A unique indicator of the stratospheric SO2-to-H2SO4 conversion process appears to be the 33S isotope anomaly, Δ33S (see Text S1 of the auxiliary material), created via mass independent fractionation (MIF) during the SO2 photochemical reaction process and retained in the oxidation end product (H2SO4) and eventually preserved in polar snow [Baroni et al., 2007; Savarino et al., 2003b]. Laboratory studies [Farquhar et al., 2001] demonstrate that the MIF isotope anomaly is generated by UV (wavelength <310 nm) photolysis of SO2. Shielding of the solar UV-B and UV-C radiation by stratospheric ozone prevents similar photolysis in the troposphere. Therefore H2SO4 from the oxidation of tropospheric SO2 carries no MIF anomaly, and only stratospheric eruptions may result in Δ33S anomaly in the H2SO4. The MIF anomaly provides a technique to distinguish climatically important stratospheric eruptions from tropospheric eruptions in polar ice cores. Volcanic sulfate of known stratospheric eruptions in the last 1000 years in Antarctica ice cores is characterized by significant non-zero Δ33S values [Baroni et al., 2007, 2008; Savarino et al., 2003b], while zero Δ33S (within the analytical uncertainty) was observed in all tropospherically produced sulfate (both volcanic and non-volcanic).

[12] Initially, the volcanic sulfate from the 1810–1811 snow layers of a few Antarctica ice cores was measured for MIF anomaly. The Δ33S of the volcanic sulfate in samples from Dome C and South Pole cores (+0.10‰ and −0.003‰, respectively, Table 1) was within the respective analytical uncertainties (±0.17‰ and ±0.12‰) of the instrumental technique, and therefore showed no anomaly. However, zero Δ33S value of a single volcanic sample does not necessarily indicate a non-stratospheric eruption. Baroni et al. [2007] discovered that the Δ33S value of a volcanic event in Antarctic snow changes with time from positive to negative during the SO2-to-H2SO4 conversion. A net zero Δ33S in all of the oxidation product of an eruption is required by 33S mass balance; thus if all H2SO4 of a stratospheric eruption is preserved in polar ice and collected in a single sample, or when a sample contains equal amount of H2SO4 with positive and negative Δ33S, the Δ33S will be zero [Baroni et al., 2007, 2008]. This is illustrated by the absence of MIF anomaly (Δ33S = −0.06‰, uncertainty ±0.12‰, Table 1) of the Kuwae sulfate in the Dome C core, compared with non-zero Δ33S (+0.25‰) of a Kuwae sample in a South Pole core. The former probably contained equal amounts of sulfate with positive and negative Δ33S, while the latter contained more sulfate with positive Δ33S. Therefore, Δ33S measurement on at least two time-resolved samples of an eruption is necessary to ascertain that the eruption is stratospheric [Baroni et al., 2007]. Owing to limited amounts of ice containing volcanic sulfate in the Antarctica cores, only one sulfate sample from the 1810–1811 snow layers at each location was obtained for Δ33S measurement and no Δ33S anomaly was found in these single samples of the event (Table 1).

Table 1. Sulfur-33 MIF values and uncertainty (‰) of volcanic sulfate from the Tambora, the 1809 and Kuwae Eruptionsa
Ice Core LocationSample TypeTambora1809 EruptionKuwae
Δ33S, ‰UncertaintyΔ33S, ‰UncertaintyΔ33S, ‰Uncertainty
  • a

    “Early” or “Late” refers to the time period during a volcanic eruption represented by the sample.

  • b

    Presented previously [Baroni et al., 2008].

Antarctica
   Dome CSingle sampleNo data +0.10±0.17−0.06b±0.12b
   South PoleSingle sample+0.15b±0.12b−0.003±0.12+0.25b±0.10b
   South PoleEarly+0.20±0.12No data +0.60±0.12
   South PoleLate−0.60±0.12No data −0.55±0.26
Greenland
   SummitEarly+0.23±0.08+0.18±0.08No data 
   SummitLate−0.28±0.08−0.12±0.08No data 

[13] The 2007 Summit, Greenland ice cores provided the first Northern Hemisphere volcanic sulfate samples for sulfur MIF anomaly measurement. Two samples (early and late deposition) of the volcanic sulfate were obtained from the 1810–1811 layers of the four cores. The Δ33S of the early volcanic sulfate is +0.18‰ and that of the late volcanic sulfate is −0.12‰, both significantly different from zero (uncertainty ±0.08‰). The two time-resolved samples of the Tambora eruption in the same cores also show positive (early) and negative (late) Δ33S values (Table 1).

[14] The Δ33S anomaly of volcanic sulfate in the 1810–1811 snow layers in Greenland and the same positive-to-negative Δ33S change for the Tambora sulfate and the earlier volcanic sulfate provide new and independent evidence that a stratospheric eruption occurred during or around the year of 1809. Because Δ33S anomaly has not been found in the 1810–1811 volcanic sulfate in Antarctica (no time-resolved sulfate samples have been obtained), the Greenland Δ33S anomaly does not directly lead to the conclusion that the 1809 stratospheric eruption occurred in the tropics and is responsible for the volcanic deposition in both polar regions. To determine whether the volcanic deposition in the 1810–1811 layers in Greenland and Antarctica came from a single eruption, we examined the precise timing of the deposition in each polar region using the sub-annually dated Antarctica and Greenland ice cores. The deposition from the Tambora eruption and from the 1809 eruption(s) can be seen in two pairs of West Antarctica and South Pole cores (Figures 1a and 1b) and in three Summit, Greenland cores (Figure 1c). From the mid-point of the Tambora deposition period to the mid-point of the deposition of the 1809 volcanic sulfate, the average lengths of time are 77 (range 75–81, Table S1 of the auxiliary material) months in Antarctica and 72 (range 71–73) months in Greenland (Table 2 and Figure 1). The overlap between these times is significant, given the uncertainty (±4 months) of the sub-annual dating (see Text S1 of the auxiliary material), and indicates that the deposition of the 1809 volcanic sulfate occurred essentially at the same time in Antarctica and in Greenland. In addition, the deposition of the 1809 volcanic sulfate lasted approximately 19 months (average deposition time in Antarctica and Greenland), very similar to that (20 months) for Tambora. Furthermore, the ratios of the deposition flux of the 1809 volcanic sulfate to that of the Tambora eruption are very similar at the two polar regions: the mean ratio is 0.45 (range 0.26–0.60) in Antarctica, compared to 0.61 (range 0.55–0.69) in Greenland (Table 2).

Figure 1.

Sulfate deposition from the Tambora and 1809 volcanic eruptions in Antarctica and Greenland ice cores. The length of a deposition period is determined by the continuous elevation of sulfate concentration above the non-volcanic background. Time difference is the length of time between the mid-point of Tambora deposition and that of the 1809 eruption.

Table 2. Timing and Volcanic Flux of the April, 1815 Tambora Eruption and the 1809 Eruption in Antarctica and Greenland Ice Corea
Ice CoreTambora1809 EruptionTime Difference (months)Ratio (f/fTambora)
Length (months)Mid-point (month)Volcanic Flux f (kg km−2)Length (months)Mid-point (month)Volcanic Flux f (kg km−2)
Antarctica
   SP01b25Jan 18176621Jun 181029790.44
   WDCc22Oct 18168122Jul 181041750.51
   SI85d  129  53 0.41
   DY89d  90  54 0.60
   Law Domee  80  45 0.56
   Plateau Remotef  22  8.3 0.37
   Dome Cg  39  10.2 0.26
   Average23  21  770.45
Greenland
   SU0717Sep 18165917Sep 181036720.60
   ST89h  47  28 0.60
   GITSi  48  33 0.69
   D3i  85  47 0.55
   Average      720.61

4. Conclusions

[15] The Δ33S anomaly of the 1809 volcanic sulfate in Greenland and the similar deposition characteristics (timing and flux) of the volcanic sulfate on opposite polar ice sheets lead us to conclude that a large stratospheric eruption occurred in 1809 and the volcano is located in the tropics. This conclusion does not preclude the possibility that contemporaneous, small or moderate eruptions occurred in the high/mid-latitudes of both hemispheres at approximately the same time; these eruptions may have left the tephra found in the Yukon (the Arctic) and Siple Dome (Antarctica) ice cores, but would have had no significant impact on the magnitude of the volcanic signals in the ice cores or on the global climate. It may also be possible that the tephra is part of the background dust particles in the atmosphere, not necessarily from contemporaneous volcanic eruptions.

[16] The probable date or month of the 1809 eruption can be determined from the ice core timing data. Tambora erupted in April, 1815 [Stothers, 1984]. The sub-annually dated ice core records show that the deposition of Tambora sulfate lasted 16–25 months (Table 2). The deposition mid-point falls in the second half (July–December) of 1816 in both polar regions, suggesting that the time for transport and deposition of volcanic aerosols at the poles from a low-latitude stratospheric eruption is approximately 18 months (from April, 1815 to October, 1816). The deposition mid-point of the 1809 eruption is in the July–September period of 1810 (Figure 1 and Table 2). Applying the 18-month transport and deposition time from the Tambora data results in a likely date of February, 1809 for the 1809 eruption. This date is tentative, owing to the uncertainties of the ice core-derived months and the actual difference between Northern and Southern Hemisphere in atmospheric meridional transport of tropical stratospheric aerosols influenced by the season and the quasi-biennial oscillation in stratospheric circulation [Trepte and Hitchman, 1992]. Nonetheless, it is possible to conclude that the eruption occurred near the beginning of 1809. This is consistent with temperature records reconstructed from tree rings and corals [Briffa et al., 1998; D'Arrigo et al., 2009] showing that the years of 1809, 1810 and 1811 were much colder than the long term temperature average.

Acknowledgments

[17] We thank Ice Coring and Drilling Services, University of Wisconsin for field assistance in the drilling of the ice cores. T. Jackson contributed to the sulfur isotope analysis. Financial support provided by NSF Office of Polar Programs via awards 0087151, 0337933, 0538553 and 0612461 to J.C-D.; 0338363 and 0612422 to M.H.T. J.S. acknowledges the French Polar Institute (IPEV) and the Institut National des Sciences de l'Univers (INSU) for financial supports through their Arctic and LEFE programs.

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