Inverted models of the deep mantle show a decorrelation between maps of shear VS and compressional VP wave velocities, an anti-correlation between the bulk sound velocity Vϕ and VS and a much larger variability of VS with respect to VP, expressed by large values of the ratio of their relative lateral variations. We carried out synthetic tests to verify if these features could be artifacts, explained by limits in tomographic resolution: synthetic data are calculated for an “input” model, and linearly inverted, as in tomography, to find an “output” model. Comparing the values of the aforementioned parameters for two different chemically homogeneous input models with the associated reconstructed output ones, we found that artifacts caused by realistic data noise and the nonuniform distribution of seismic sources and stations over the globe are not sufficient to introduce the features previously described. We confirm that compositional effects are required to explain them.
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 In a chemically homogeneous mantle, where seismic heterogeneity is caused by thermal anomalies alone, we expect RS,P < 2.5 [Karato, 2003] and high rP,S and rϕ,S [Hirose, 2006]. The aforementioned results indicate that chemical composition has an influence on seismic heterogeneity, at least in the lowermost mantle.
 It has nonetheless been suggested by Schuberth et al.  that “isochemical whole-mantle flow with strong core heating and a pyrolite composition can be reconciled with tomography”. This is in contrast with the statement by Ritsema et al.  that “Temperature anomalies in the thermochemical model resemble the spatial extent of low seismic velocity anomalies and the shear velocity spectrum in the D″ region better than the isochemical model.”
 Both Ritsema et al.  and Schuberth et al.  evaluate tomographic resolution of S-wave travel-time data only. We extend their treatment to P-wave tomography to determine if low resolution of seismic tomography can explain inconsistencies from an isochemical model. We apply the tomography resolution operator associated with common P and S travel-time coverage to isochemical mantle models, and verify whether or not values of rP,S, rϕ,S and RS,P found from the data can be explained as artifacts of low tomographic resolution.
2. S- and P-Travel-Time Tomography
 We invert body-wave travel-time delays in the regularized least-squares framework of Boschi and Dziewonski . In both P- and S-wave inversions, we consistently select the solution from the “corner-region” of the L-curve [Hansen, 1992], while checking its general consistency with other recent mantle tomography results [e.g., Boschi et al., 2007, 2008].
 The inverted model is parameterized with 5° size blocks horizontally and 29 layers vertically. We employ ≈620,000 direct P-wave arrivals based on the ISC bulletin with sources relocated by Antolik et al.  and ≈170,000 S-wave ones measured via cross-correlation by Houser et al. . The data were corrected for crustal structure by the authors. S-wave arrivals are much fewer than P-wave ones because of the inherent difficulty of making an S-wave travel-time pick with respect to a P-wave one.
 The results of the inversions are shown in Figure 1. The main subduction zones and cratonic regions are visible in both VP (Figure 1a) and VS (Figure 1b). A smaller variability is observed in the mid-mantle. In the lowermost mantle, the two large low-velocity provinces under Africa and the Pacific are reproduced in both VS and, to some extent, VP [e.g., Wang and Wen, 2004; Hernlund and Houser, 2008].
 We calculate Vϕ and δ (lnVϕ) based on equations (1) and (2) of Masters et al. , and then find rϕ,S, rP,S and RS,P as functions of depth as defined in Section 1. In the calculation of RS,P we discard the points in which either ∣δ (lnVS)i − ∣ < 0.2% or ∣δ (lnVP)i − ∣ < 0.2%. This way and with the definition of equation (2) we remove the arbitrariness of the reference model choice and the values that cannot be distinguished from numerical noise.
Figure 2 shows rϕ,S, rP,S and RS,P from the tomographic maps of Figure 1. rP,S is significantly positive throughout the mantle, but, consistently with Figure 10 of Becker and Boschi , it decreases in the bottom 300 km, where the phase transition from perovskite to post-perovskite is thought to occur [e.g., Oganov and Ono, 2004]. In the mid- and deep mantle rϕ,S is always significantly negative, with a noticeable decrease between 1500 and 2000 km and the last 300 km of mantle. If we compare this result, e.g., with Figure 9 of Antolik et al. , we notice that for both the value of the correlation in the mid-mantle is ≈−0.5, but in Figure 2 it decreases in the lowermost mantle, whereas the correlation of Antolik et al.  does not vary with respect to the above layers. The values of RS,P in the lowermost mantle are > 2.5, indicating a larger lateral variability of VS with respect to VP. From Karato , as already reminded in Section 1, we know that values RS,P > 2.5 cannot be explained by a chemically homogeneous mantle circulation model. We then conclude that, at least in the last 300 km of mantle, all these results are an indication of the importance of compositional effects [e.g., Karato and Karki, 2001]. We are skeptical about the sudden decrease of rP,S and RS,P right above the core-mantle boundary (CMB): our datasets only include direct phases, and, in the absence of core-reflected/refracted ones, resolution will tend to drop at the very bottom of the mantle, so that this effect could be an artifact.
3. Synthetic Experiments
 The results summarized in Section 2 point to the existence of compositional heterogeneities. Yet, it is a priori possible that the decorrelation and high ratio between δ (lnVS) and δ (lnVP) can be caused by the uneven lateral and radial coverage of the seismic datasets, and to the differences in sampling between S- and P-waves. δ (lnVP) and δ (lnVS) are well resolved over different volumes of the mantle, which will systematically lower the correlation of their tomographic images. The tomography resolution operator R shows how real Earth properties are mapped into a tomographic model [e.g., Boschi, 2003; Ritsema et al., 2007; Bull et al., 2010]. To verify if resolution has significant effects on the measurements of rP,S, rϕ,S and RS,P, we generate synthetic travel-time delays from a known input model, making use of the same stations and sources of Antolik et al.  and Houser et al. . We follow the ray-theory approximation on a 1-D reference model, resulting in a linear relation between model anomalies and data. Details are given by, e.g., Boschi and Dziewonski . The generated data include Gaussian noise with a standard deviation of 1 s for P waves and 3 s for S waves. We invert those data with the same procedure employed in Section 2 and the same regularization parameters of the solutions shown in Figure 1, calculate the correlations rP,S and rϕ,S and the ratio RS,P for both the input and the reconstructed model and compare them to evaluate the effects of tomographic resolution. This is equivalent, given an input model m, to comparing m and R · m. Schuberth et al.  conducted a similar experiment, but limited their analysis to S-wave tomography. We repeat this procedure for two models that reproduce the behavior of an isochemical mantle:
 1. The first model has the VS distribution of SMEAN of Becker and Boschi , while the VP anomalies are simply obtained by multiplying the values of VS anomalies by of 0.45 (hereafter, this model will be denoted as 045S-SMEAN), based on the results from Figure 2 of Karato . The model has rϕ,Sin = rP,Sin = 1 and RS,Pin = 2.22 constant at all layers (Figure 3).
 2. The second one is a purely thermal mantle circulation model, whose details are given by Nakagawa et al. . This model has material properties calculated using a self-consistent mineralogical treatment based on minimization of free energy, i.e., the scaling between temperature and (VS,VP) is not a-priori linear. From Figure 4 one can see that, as expected, both the input correlations rϕ,Sin and rP,Sin are very close to 1, except right below the region where the phase transition from ringwoodite to perovskite and magnesiowüstite occurs [Ono and Oganov, 2005].
3.1. Resolution of Model 045S-SMEAN
 We compare in Figure 3 the values of rϕ,S, rP,S and RS,P associated with model 045S-SMEAN, with those found from the inversion of 045S-SMEAN-generated data.
 The correlation rϕ,Sout for the reconstructed model changes significantly in the upper mantle, where our database, that contains only direct body waves, has very limited resolution [Boschi, 2003]. In the lower mantle, from a depth of about 1800 km, the correlation is 0.97, indicating that limits in tomography resolution do not significantly deteriorate the complete correlation between Vϕ and VS variations; rP,Sout is even less perturbed with respect to rP,Sin = 1. This happens because Vϕ is a function of VP and VS, so the uncertainties on Vϕ are larger than those on VP or VS. We observe a similar behavior for the ratio RS,P, which is almost the same for the input (red curve) and the output (black curve) model between 1500 and 2500 km depth. There is a slight decrease of RS,Pout right at the CMB, owing probably to the data-coverage problems mentioned in Section 2.
3.2. Resolution of a Geodynamical Isochemical Model
 The model of the previous section is unrealistic, since it does not include phase transitions that can still occur in a purely thermal model. We therefore generate and invert a synthetic dataset based on a geodynamical model by Nakagawa et al. .
 The results (Figure 4) are similar to those of Section 3.1. Both the correlations in the output model rϕ,Sout and rP,Sout are always significant with a confidence level higher than 99% and similar to the associated input rϕ,Sin and rP,Sin, but we cannot reconstruct the sudden decrease of correlation at 850 km of the input model mentioned in Section 3. In the bottom mantle layer both rP,Sout and rϕ,Sout decrease, but, as mentioned, resolution within this layer is low. The comparison between RS,Pin and RS,Pout is good from 1600 km depth down, the region where the datasets of direct arrivals that we employed have higher resolution [Boschi, 2003].
4. Discussion and Conclusions
 We have inverted P- and S-wave travel-times as illustrated in Figure 2 and discussed in Section 2.
 We confirm a significant anti-correlation between Vϕ and VS, with a relevant decrease of rϕ,S between 2500 km and the CMB. Correlation rP,S is high at all mantle depths, except for the bottom 100 km. The ratio RS,P also drops in our lowermost mantle layer, but is very large (i.e., >2.5) between 2500 and 2800 km depth, with a sharp change from RS,P ≈ 2.5 to RS,P ≈ 3.0 at 2500 km. The very bottom layer (2800–2900 km) in our parameterization is only sampled by the small subsets of P and S travel-times whose associated ray paths bottom in this depth range, with inherent resolution problems; we do not attribute much significance to the bottom layer, but consider our results robust over the rest of the lower mantle. The upper mantle is also notoriously under-sampled by body waves [e.g., Boschi and Dziewonski, 1999].
 Our results are first of all consistent with studies that indicate the presence of a compositional signature on deep-mantle seismic velocities. For example, Cammarano et al.  show the importance of compositional effects on the ratio RS,P through the whole mantle. Tsuchiya et al.  give an alternative explanation, showing from first principle calculations that post-perovskite, likely the most abundant phase in the D″, has larger VS than Vϕ variations. From similar ab initio calculations Wookey et al.  obtained for post-perovskite values of rϕ,S < 0.
 Secondly, other seismic studies have also shown the importance of compositional effects in the deep mantle. For instance, Trampert et al.  employed probabilistic tomography to highlight the importance of compositional effects on seismic velocities in the lower mantle. More recently, Hernlund and Houser  have compared different tomographic models and showed that the distributions of VP and VS are uncoupled in the deep mantle. Similarly, Boschi et al. [2007, 2008] show that presumed lowermost mantle plumes have a different signature in P- vs. S-velocity tomography.
 Last, results in geodynamical models have shown the importance of compositional effects. For example, Tan and Gurnis  have shown the effects on seismic velocities of a chemical layer at the base of the mantle and its possible evolution in time. Tackley  indicated that a mixed thermo-chemical mantle model is probably closest to the true Earth's mantle model. Nakagawa et al.  have evidenced the importance of small variations in MORB composition on mantle circulation.
 In Section 3, we addressed the question of whether the existence of compositional heterogeneity in the mantle, as it is currently inferred from tomography, can be interpreted as an artifact caused by low seismic resolution. To solve this problem, we performed two synthetic resolution tests with input models that reproduce the seismic characteristics of a purely thermal mantle circulation.
 We first tested how our data resolve a model with perfect correlation between lateral VP and VS variations, and found that from 1500 km down this property is essentially reproduced by the reconstructed model. Additionally, the input model had RS,Pin = 2.2 constant for all the layers, and this essentially holds for the output model from 1500 km down.
 We conducted an analogous test, inverting a synthetic dataset generated from the seismic velocity structure associated with the isochemical geodynamical model of Nakagawa et al. . The input model had both rϕ,Sin = rP,Sin = 1, except for the 800–900 km layer. In the reconstructed model this feature is smeared over a wide depth-range, but, besides this effect, the correlation is always significantly positive. From 1800 km down, the values of RS,P for the input and output model are very similar, indicating again that the dataset that we generated has enough resolution in this depth-range.
 These tests confirm that seismic resolution of lower mantle is sufficient to constrain rϕ,S, rP,S and RS,P consistently.
 Fabio Cammarano contributed to this work with many insightful comments. We thank Christine Houser for sharing her S-travel-time database.
 The Editor thanks Mark Panning and an anonymous reviewer for their assistance in evaluating this paper.