Landscape-level controls on dissolved carbon flux from diverse catchments of the circumboreal
Article first published online: 21 AUG 2012
©2012. American Geophysical Union. All Rights Reserved.
Global Biogeochemical Cycles
Volume 26, Issue 4, December 2012
How to Cite
2012), Landscape-level controls on dissolved carbon flux from diverse catchments of the circumboreal, Global Biogeochem. Cycles, 26, GB0E02, doi:10.1029/2012GB004299., , , , , , and (
- Issue published online: 21 AUG 2012
- Article first published online: 21 AUG 2012
- Manuscript Accepted: 6 JUL 2012
- Manuscript Revised: 28 JUN 2012
- Manuscript Received: 1 FEB 2012
- National Sciences Foundation. Grant Number: OPP-0732985
- Natural Sciences and Engineering Research Council of Canada. Grant Number: Postdoctoral Fellowship
- dissolved organic carbon;
 While much of the dissolved organic carbon (DOC) within rivers is destined for mineralization to CO2, a substantial fraction of riverine bicarbonate (HCO3−) flux represents a CO2 sink, as a result of weathering processes that sequester CO2 as HCO3−. We explored landscape-level controls on DOC and HCO3− flux in subcatchments of the boreal, with a specific focus on the effect of permafrost on riverine dissolved C flux. To do this, we undertook a multivariate analysis that partitioned the variance attributable to known, key regulators of dissolved C flux (runoff, lithology, and vegetation) prior to examining the effect of permafrost, using riverine biogeochemistry data from a suite of subcatchments drawn from the Mackenzie, Yukon, East, and West Siberian regions of the circumboreal. Across the diverse catchments that we study, controls on HCO3−flux were near-universal: runoff and an increased carbonate rock contribution to weathering (assessed as riverwater Ca:Na) increased HCO3− yields, while increasing permafrost extent was associated with decreases in HCO3−. In contrast, permafrost had contrasting and region-specific effects on DOC yield, even after the variation caused by other key drivers of its flux had been accounted for. We used ionic ratios and SO4 yields to calculate the potential range of CO2sequestered via weathering across these boreal subcatchments, and show that decreasing permafrost extent is associated with increases in weathering-mediated CO2 fixation across broad spatial scales, an effect that could counterbalance some of the organic C mineralization that is predicted with declining permafrost.