Infrared emissivities of silicates: Experimental results and a cloudy atmosphere model of Spectral emission from condensed particulate mediums


  • James E. Conel


Infrared emissivities of powered silicates are shown by experiment to contain new maximums and minimums that are representative of both composition and particle size. A cloudy atmosphere model for radiative transfer in a condensed powder is developed in which the scatter is considered to be both nonconservative and linearly anisotropic. The scattering parameters are computed as functions of frequency from the Mie diffraction theory. Detailed calculations of the spectral emissivity of quartz are presented. The model is shown to account for many features observed experimentally in the spectrums of quartz powders and sand. Changes in the spectrum with particle size can be understood in terms of changes in the albedo for single scattering and the degree of forward scatter with particle size. The principal Christiansen frequencies of silicate powder films obtained from transmission measurements are shown to be diagnostic of mineralogy and to be frequencies of maximum emissivity for powders. The relationship is discussed in detail for quartz.