Present address: Department of Geology and Geophysics, Grant Institute, University of Edinburgh, Edinburgh EH9 3JW, UK (E-mail: Gavin.England@glg.ed.ac.uk)
Palaeoenvironmental significance of rounded pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Basin: oxygen-deficient atmosphere or hydrothermal alteration?
Version of Record online: 11 DEC 2002
Volume 49, Issue 6, pages 1133–1156, December 2002
How to Cite
England, G. L., Rasmussen, B., Krapez, B. and Groves, D. I. (2002), Palaeoenvironmental significance of rounded pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Basin: oxygen-deficient atmosphere or hydrothermal alteration?. Sedimentology, 49: 1133–1156. doi: 10.1046/j.1365-3091.2002.00479.x
- Issue online: 11 DEC 2002
- Version of Record online: 11 DEC 2002
- Manuscript received 10 May 2001; revision accepted 14 March 2002.
- Archaean atmosphere;
- sulphur isotopes;
Petrographic and sulphur isotope studies support the long-held contention that rounded grains of pyrite in siliciclastic sequences of the Late Archaean Witwatersrand Supergroup originated as placer grains. The grains are concentrated at sites where detrital heavy minerals are abundant within quartz-pebble conglomerates and quartzose sandstones. Depositional sites with abundant pyrite are: (1) within the matrix of bar-type, clast-supported conglomerates; (2) on scoured or winnowed surfaces; and (3) on stratification planes. The grains are internally compact or porous, with truncation of internal structure at outer margins indicating fragmentation and rounding of pyritic source-rocks during erosion and sediment transport. A large range in textures reflects source-rock lithologies, with known varieties linked to sedimentary-hosted diagenetic pyrite, volcanic-hosted massive sulphide deposits and hydrothermal pyrite. Laser ablation sulphur isotope analysis of pyrite reveals a broader range in δ34S values (− 5·3 to + 6·7‰) than that of previously reported conventional bulk-grain analyses (− 1 to + 4‰). Rounded pyrite from the Steyn Reef has significant variation in δ34S values (− 4·7 to + 6·7‰) that establishes heterogeneous sulphur compositions, with even adjacent grains having diverse isotopic signatures. The heterogeneity supports a placer origin for rounded pyrite. Euhedral pyrite and pyrite overgrowths which are undoubtedly authigenic have restricted δ34S values (− 0·5 to + 2·5‰), are chemically distinct from rounded pyrite and are probably the products of metamorphism or hydrothermal alteration. The placer origin of rounded pyrite indicates that pyrite was a stable heavy mineral during erosion and transport in the early atmosphere. Its distribution in three sequences (Witwatersrand Supergroup, Ventersdorp Contact Reef and Black Reef), and in other sequences not linked to Witwatersrand-type Au-U ore deposits, implies deposition of redox-sensitive detrital heavy minerals during the Late Archaean. Consequently, rounded grains of detrital pyrite are strong indicators of an oxygen-poor atmosphere. While not confirming a placer origin for gold in Witwatersrand Au-U ore deposits, the palaeoenvironmental significance of rounded pyrite negates its link to hydrothermal mineralization.