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(2,2′-Bipyridine-κ2N,N′)bis(5-thioxo-1,5-dihydro-1,3,4-thiadiazole-3-thiolato-κS)zinc(II)
DOI: 10.1107/S160053680704010X
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How to Cite
Zhang, X.-L., Qiu, Y.-E., Zhang, C.-L. and Xin, B.-W. (2007), (2,2′-Bipyridine-κ2N,N′)bis(5-thioxo-1,5-dihydro-1,3,4-thiadiazole-3-thiolato-κS)zinc(II). Acta Cryst. E, 63: m2381–m2382. doi: 10.1107/S160053680704010X
In the crystal structure of the title compound, [Zn(C2HN2S3)2(C10H8N2)], a twofold rotation axis passes through the Zn atom and the midpoint of the C—C bond linking the two pyridine rings. The ZnII atom is located on a 21 axis and is coordinated by two thiolate S atoms of different 5-thioxo-1,5-dihydro-1,3,4-thiadiazole-3-thiolate ligands and two N atoms of a 2,2′-bipyridine ligand in a tetrahedral geometry, with a Zn—S distance of 2.3204 (8) Å and a Zn—N distance of 2.061 (2) Å. In addition, mononuclear molecules are linked together to form a one-dimensional chain by N—H...S hydrogen bonds.