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ajgw12061-sup-0001-figures1.tif32KFigure S1. Electrospray ionisation collision-induced dissociation–tandem mass spectrometry [(ESI(+)-CID-MS/MS] product ion spectra using [Y0]+ as precursor ion for (a) Mv-3-glc (cone voltage 45 V, collision energy 35 eV), (b) Mv-3-glc-acetaldehyde (cone voltage 60 V, collision energy 35 eV), (c) Mv-3-glc-4-vinylphenol (cone voltage 45 V, collision energy 35 eV) and (d) Mv-3-glc-4-vinylcatechol (cone voltage 60 V, collision energy 35 eV).
ajgw12061-sup-0002-figures2.tif19KFigure S2. Electrospray ionisation collision-induced dissociation–tandem mass spectrometry [(ESI(+)-CID-MS/MS] product ion spectra using [Y0]+ as precursor ion for (a) Pn-3-glc (cone voltage 45 V, collision energy 35 eV) and (b) Pn-3-glc-pyruvic acid (cone voltage 60 V, collision energy 35 eV).
ajgw12061-sup-0003-figures3.tif17KFigure S3. Electrospray ionisation collision-induced dissociation–tandem mass spectrometry [(ESI(+)-CID-MS/MS] product ion spectra using [Y0]+ as precursor ion for (a) Dp-3-glc (cone voltage 45 V, collision energy 35 eV) and (b) Dp-3-glc-4-vinylphenol (cone voltage 60 V, collision energy 35 eV).
ajgw12061-sup-0004-figures4.tif24KFigure S4. Electrospray ionisation collision-induced dissociation–tandem mass spectrometry [(ESI(+)-CID-MS/MS] product ion spectra using [Y0]+ as precursor ion for (a) Pt-3-glc (cone voltage 45 V, collision energy 35 eV), (b) Pt-3-glc-4-vinylphenol (cone voltage 60 V, collision energy 35 eV) and (c) Pt-3-glc-4-vinylcatechol (cone voltage 45 V, collision energy 35 eV).
ajgw12061-sup-0005-figures5.tif14KFigure S5. (a) Electrospray ionisation mass spectrometry [ESI(+)–MS] spectrum for Mv-3-glc-(+)-catechin (cone voltages 45 and 60 V); (b) Electrospray ionisation collision-induced dissociation–tandem mass spectrometry [(ESI(+)-CID-MS/MS] product ion spectra using [M]+ and [Y0]+ as precursor ions for Mv-3-glc-(−)-epicatechin (cone voltage 30 V, collision energy 25 eV for molecular ion [M]+ and 60 V and 35 eV for aglycone ion [Y0]+).

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