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Fig. S1. Enzyme assisted catalysis through a water molecule in aspartyl dipeptidase (PDB 1FY2) and enzyme assisted catalysis in glutamate carboxypeptidase II (PDB 3BXM).

Doc. S1. General interactions in the active site of amidases.

Doc. S2. Low barrier hydrogen bonds (LBHBs).

Doc. S3. The histidine ring flip mechanism.

Doc. S4. Methods summary.

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