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Fig. S1 UV–vis absorption at 392 nm of a 20 μm methanobactin (mb) solution titrated with CuCl2 at pH 6.

Fig. S2 Half-lives for ligands exchange reactions as a function of Cu activity at pH 8 and pH 6 for k1 and k2.

Fig. S3 Temperature-dependence of the ligand exchange reaction rate k2.

Fig. S4 Separation of Cu-free and Cu-bound methanobactin (mb) complexes by size-exclusion chromatography.

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