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Figure S1 The chromatograms of degradation products of aloin A under different temperature (a), light (b) and pH (c) conditions.

Figure S2 The chromatograms of degradation of aloin A at different time points at 50 °C (a) and pH 5.0 (b) and under light condition (c).

Table S1 1H NMR data of 10-hydroxyaloin B (1), 10-hydroxyaloin A (2), elgonica-dimer B (3) and elgonica-dimer A (4) in MeOH-d4.

Table S2 13C NMR data of 10-hydroxyaloin B (1), 10-hydroxyaloin A (2), elgonica-dimer B (3) and elgonica-dimer A (4) in MeOH-d4.

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