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Temperature-Insensitive Large Strain of (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3–(K0.5Na0.5)NbO3 Lead-Free Piezoceramics

Authors

  • Klaus T. P. Seifert,

    1. Institute of Materials Science, Technische Universität Darmstadt, Petersenstrasse 23, Darmstadt 64287, Germany
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  • Wook Jo,

    Corresponding author
    1. Institute of Materials Science, Technische Universität Darmstadt, Petersenstrasse 23, Darmstadt 64287, Germany
      †Author to whom correspondence should be addressed. e-mail: jo@ceramics.tu-darmstadt.de
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  • Jürgen Rödel

    1. Institute of Materials Science, Technische Universität Darmstadt, Petersenstrasse 23, Darmstadt 64287, Germany
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  • J. L. Jones—contributing editor

  • This work was financially supported by the Deutsche Forschungsgemeinschaft (DFG) under SFB 595, A1.

†Author to whom correspondence should be addressed. e-mail: jo@ceramics.tu-darmstadt.de

Abstract

The effect of (K0.5Na0.5)NbO3 (KNN) addition on the ferroelectric behavior of (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3 (BNT–BKT) lead-free piezoceramics was investigated. Polarization and strain hysteresis loops indicate that the ferroelectric order is disrupted significantly with the addition of KNN as a replacement for BNT and the destabilization of the ferroelectric order is accompanied by an enhancement of the unipolar strain, which peaks at a value of ∼0.48% (corresponding to a large signal d33 of ∼600 pm/V) at 1 mol% KNN content. This strain was analyzed as derived from an electrostrictive effect at lower electric fields and a converse piezoelectric effect at higher electric fields. By limiting the electric driving field to exclude the contribution from the converse piezoelectric effect, a temperature-insensitive large-field d33 of ∼250 pm/V up to 200°C was achieved.

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