Hydrothermal Synthesis and White Luminescence of Dy3+-Doped NaYF4 Microcrystals

Authors


  • R. S. Hay—contributing editor

  • This study was financially supported by Pukyong National University in the 2010 Post-Doc and this work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MEST) (No. 2010-0029885) Program also this work was partially supported by NCRC (National Core Research Center) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (2010-0001-226).

†Author to whom correspondence should be addressed. e-mail: jhjeong@pknu.ac.kr

Abstract

2 mol% Dy3+-doped NaYF4 microcrystals with different morphologies and crystalline phases have been synthesized through a hydrothermal method without assistance of any surfactant, catalyst, or template by controlling reaction temperatures, reaction time, and molar ratios of reactants. For comparison, the samples were also synthesized by a direct coprecipitation method. The final products were characterized by X-ray diffraction, field emission scanning electron microscopy, photoluminescence excitation and emission spectra, and luminescent dynamic decay curves. Dy3+ exhibits bright white light under near ultraviolet 350 or 351 nm excitation and the white light was evaluated by chromaticity coordinates. The experimental results suggest that the obtained Dy3+-doped NaYF4 microcrystals have potential applications in white light materials.

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