Changes in chemical composition, physical property and microstructure of pidan white were monitored during pickling in the presence of different divalent (CaCl2, MgCl2) and monovalent (KCl) cations at different levels (0.2 and 0.5%) up to 3 weeks, followed by aging for another 3 weeks. Pidan prepared following the commercial process, in which 0.2% PbO2 or 0.2% ZnCl2 was incorporated, was also tested. Hardness, cohesiveness and adhesiveness of pidan white gradually increased during pickling, but these parameters decreased during aging time (P < 0.05), regardless of cations used. Nevertheless, pidan white treated with 0.2% PbO2 retained hardness and cohesiveness but had a slight decrease in adhesiveness, when pickling/aging time increased up to week 6 (P < 0.05). Transmission electron microscopic studies indicated that the aggregation of egg proteins took place in pidan white gels treated with 0.2% PbO2, 0.2% ZnCl2 or 0.2% CaCl2 during pickling. However, the degree of aggregation varied with cations used.