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Figure S1. Scheme of the photocatalytic reaction system.

Figure S2. Schematic diagram of the electrochemical apparatus.

Figure S3. XPS spectra of V3d, O1s and Sm3d5/2.

Figure S4. RhB adsorption on Ag/SmVO4 composites with different Ag concentration (a) and different heating temperature (b) in the dark.

Figure S5. First-order kinetics plot for the photodegradation of RhB by different photocatalysts.

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