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Table S1. 1H and 13C NMR assignment of the major metabolites identified in polar extracts (MeOD - D2O 1:1, pH 6.0) of Quercus Ilex. Samples were measured at a magnetic field of 600 MHz and at a temperature of 298.0 K. Chemical shifts were referenced to TSP. (The detailed assignment of the NMR signals of the polar and nonpolar metabolic profiles of Q. Ilex leaves are shown in Tables S1 and S2. Table S3 shows the results of t-tests for comparisons between control and wounded plants in metabolite peak areas of the different metabolites.)

Table S2. 1H and 13C NMR assignment of the major metabolites identified in nonpolar extracts (CDCl3) of Quercus Ilex. Samples were measured at a magnetic field of 600 MHz and a temperature of 298.0 K. Chemical shifts are referenced to TMS.

Table S3. t-test statistics for comparisons of peak areas of different metabolites in control and wounded plants.

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