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Michaela Klotz, Idris Amirouche, Christian Guizard, Céline Viazzi and Sylvain Deville Ice Templating—An Alternative Technology to Produce Micromonoliths Advanced Engineering Materials 14

Version of Record online: 20 JUN 2012 | DOI: 10.1002/adem.201100347

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Zirconia micromonoliths prepared by the ice-templating method and sintered at high temperature present unique macroporous structures and mechanical properties of potential interest as catalyst carrier. The use of specific ice-shaping compounds in the ice-templating process leads to a honeycomb-like structure with hexagonally shaped microchannels running continuously throughout the micromonolith. The microchannels can be advantageously used for the deposition of a catalytically active meso/microporous layer, yielding a hierarchic porous structure which should facilitate access to the catalytic sites.

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