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E. Terazzi, S. Suarez, S. Torelli, H. Nozary, D. Imbert, O. Mamula, J.-P. Rivera, E. Guillet, J.-M. Bénech, G. Bernardinelli, R. Scopelliti, B. Donnio, D. Guillon, J.-C. G. Bünzli and C. Piguet Introducing Bulky Functional Lanthanide Cores into Thermotropic Metallomesogens: A Bottom-Up Approach Advanced Functional Materials 16

Version of Record online: 8 DEC 2005 | DOI: 10.1002/adfm.200500195

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Judicious tailoring of molecular shapes and interfaces in lanthanide complexes (see Figure) can produce rational control of the thermodynamic parameters responsible for the formation of thermotropic liquid-crystalline phases with predetermined macroscopic organizations. These complexes and their specific metal-centered luminescence can be exploited for probing phase transitions and microscopic environments in mesophases.

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