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O-P. Kwon, S.-J. Kwon, M. Jazbinsek, A. Choubey, V. Gramlich and P. Günter New Organic Nonlinear Optical Polyene Crystals and Their Unusual Phase Transitions Advanced Functional Materials 17

Version of Record online: 29 JUN 2007 | DOI: 10.1002/adfm.200600494

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Nonlinear optical polyene crystals containing pyrrolidine donors (see figure) exhibit a large macroscopic second-order nonlinearity and unusual reversible or irreversible thermally induced phase transitions, changing the crystal symmetry from higher symmetry to lower symmetry with increasing temperature.

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