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Lin Tan, Lei Zhang, Xi Jiang, Xiaodi Yang, Linjun Wang, Zhaohui Wang, Liqiang Li, Wenping Hu, Zhigang Shuai, Lin Li and Daoben Zhu A Densely and Uniformly Packed Organic Semiconductor Based on Annelated β-Trithiophenes for High-Performance Thin Film Transistors Advanced Functional Materials 19

Article first published online: 12 DEC 2008 | DOI: 10.1002/adfm.200800933

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A novel semiconductor based on annelated β-trithiophenes is shown to possess an extraordinarily compressed packing mode combining edge-to-face π–π interactions and S…S interactions in single crystals (see figure), which is favorable for more effective charge transporting. Accordingly, a device incorporating this semiconductor shows remarkably high charge carrier mobility and on/off ratio of 4.6 × 107 for vacuum-deposited thin films.

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