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Michael Riskin, Ran Tel-Vered and Itamar Willner Thermo-Switchable Charge Transport and Electrocatalysis Using Metal-Ion-Modified pNIPAM-Functionalized Electrodes Advanced Functional Materials 19

Article first published online: 2 JUL 2009 | DOI: 10.1002/adfm.200900268

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Controllable phase-transition temperature of a thermosensitive polymer can be achieved by the incorporation of metal ions (Ag+, Cu2+, Hg2+). The nature of the ions does not only affect the gel-to-solid phase transition temperature, but the electro-reduced metallic nanoclusters in the polymers also yield matrices with temperature-switchable conductivity and temperature-dependent electrocatalytic behavior.

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