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Stijn Verlaak, David Beljonne, David Cheyns, Cedric Rolin, Mathieu Linares, Frédéric Castet, Jérôme Cornil and Paul Heremans Electronic Structure and Geminate Pair Energetics at Organic–Organic Interfaces: The Case of Pentacene/C60 Heterojunctions Advanced Functional Materials 19

Version of Record online: 26 OCT 2009 | DOI: 10.1002/adfm.200901233

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The electronic structure at the hetero-interface between organic semiconductors is revealed by microelectrostatic calculations for the case of a junction of pentacene with C60 fullerene. The strong discontinuity in quadrupole field provokes band bendings and level shifts, with consequences for geminate polaron-pair dissociation at such interfaces.

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