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James M. Perkins, Sarah Fearn, Stuart N. Cook, Rajagopalan Srinivasan, Chris M. Rouleau, Hans M. Christen, Geoff D. West, Richard J. H. Morris, Hamish L. Fraser, Stephen J. Skinner, John A. Kilner and David W. McComb Anomalous Oxidation States in Multilayers for Fuel Cell Applications Advanced Functional Materials 20

Version of Record online: 2 JUL 2010 | DOI: 10.1002/adfm.201000279

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Multilayer ceria/doped ceria (CeO2/Ce0.85Sm0.15O2) thin films are grown on MgO substrates by pulsed laser deposition. Ceria valence state is mapped using high resolution scanning transmission electron microscopy (STEM), showing discrete regions of 3+ and 4+ ceria cations. This anomaly is relevant to the oxygen ion conductivity of the thin film.

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