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Wei Zhang, Kenji Ochi, Michiya Fujiki, Masanobu Naito, Masaaki Ishikawa, Kei-ichi Kaneto, Wataru Takashima, Akinori Saeki and Shu Seki Programmed High-Hole-Mobility Supramolecular Polymers from Disk-Shaped Molecules Advanced Functional Materials 20

Version of Record online: 3 SEP 2010 | DOI: 10.1002/adfm.201001072

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Soluble ttbPcAlF self-assembles into 2D arrays of very-high-MW 1D-Pc supramolecular polymers. 1D-ttbPcAlF with a cofacial ring spacing of ∼0.36 nm and an interchain distance of ∼1.7 nm, self-assemblies into 2D-nanosheets (∼140 nm in length, ∼20 nm in width). The film shows a minimum hole-mobility of ∼0.3 cm2 V−1 s−1 and a fairly high dark dc-conductivity of ∼1 × 10−3 S cm−1.

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