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Kamal Asadi, Harry J. Wondergem, Reza Saberi Moghaddam, Christopher R. McNeill, Natalie Stingelin, Beatriz Noheda, Paul W. M. Blom and Dago M. de Leeuw Spinodal Decomposition of Blends of Semiconducting and Ferroelectric Polymers Advanced Functional Materials 21

Version of Record online: 7 FEB 2011 | DOI: 10.1002/adfm.201001505

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The operation of resistive switches based on phase-separated blends of organic ferroelectrics and semiconductors depends significantly on the microstructure of such systems. The blend phase separates into amorphous rir-P3HT domains embedded in a crystalline P(VDF-TrFE) matrix with an unexpectedly mono-disperse domain-size distribution for a given rir-P3HT:P(VDF-TrFE) ratio. A simple model is used to interpret the out of plane current through the film as a function of blend composition.

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