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Young Gon Seo, Kyoungja Woo, Junkyung Kim, Hyunjung Lee and Wonmok Lee Rapid Fabrication of an Inverse Opal TiO2 Photoelectrode for DSSC Using a Binary Mixture of TiO2 Nanoparticles and Polymer Microspheres Advanced Functional Materials 21

Version of Record online: 14 JUN 2011 | DOI: 10.1002/adfm.201002489

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Induced by accelerated solvent evaporation during the colloidal self-assembly process, a binary composite film of polystyrene (PS)/TiO2 is directly fabricated on a fluorine doped tin oxide (FTO) glass substrate, which exhibits a highly ordered opalline structure of PS embedded into the TiO2 matrix. By thermal calcinations without delamination, the composite film was successfully converted to the inverse-opal (IO) TiO2 film, which can be directly used as a functional film such as a photoelectrode for DSSC (dye-sensitized solar cells).

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