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Chin-Hsien Chen, Fang-Iy Wu, Yin-Yen Tsai and Chien-Hong Cheng Platinum Phosphors Containing an Aryl-modified β-Diketonate: Unusual Effect of Molecular Packing on Photo- and Electroluminescence Advanced Functional Materials 21

Version of Record online: 24 JUN 2011 | DOI: 10.1002/adfm.201100165

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The molecular packing of FPt1 analogues shows strong correlation with their emission spectra. In the crystalline state, mCzP-FPt forms dimers having a close Pt–Pt contact (3.49 Å) and gives off a broadband orange emission; however, the other complexes without intermolecular Pt–Pt interaction (>4.50 Å) but with ππ or Pt–π interaction give structured green emissions.

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