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Xiaowei Zhao, Wenzui Jin, Jinguang Cai, Jianfeng Ye, Zhenhu Li, Yurong Ma, Jinglin Xie and Limin Qi Shape- and Size-Controlled Synthesis of Uniform Anatase TiO2 Nanocuboids Enclosed by Active {100} and {001} Facets Advanced Functional Materials 21

Article first published online: 25 JUL 2011 | DOI: 10.1002/adfm.201100629

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Uniform, well-defined, tetragonal nanocuboids of anatase TiO2 enclosed by active {100} and {001} facets over a wide size range with controllable aspect ratios are solvothermally synthesized through hydrolysis of titanium tetraisopropoxide, using acetic acid as the solvent and 1-butyl-3-methylimidazolium tetrafluoroborate as the capping agent. The obtained anatase TiO2 nanocuboids exhibit interesting self-assembly behavior, remarkable crystalline phase stability, and enhanced photocatalytic activity.

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