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Chilin Li, Lin Gu and Joachim Maier Enhancement of the Li Conductivity in LiF by Introducing Glass/Crystal Interfaces Advanced Functional Materials 22

Version of Record online: 23 JAN 2012 | DOI: 10.1002/adfm.201101798

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Arrhenius plots of lithium fluoride thin films grown on silica substrates during various heating–stabilization–cooling cycles allow three Li+-migration paths in the inner film, with different local conductivities, to be distinguished. A remarkable enhancement of the Li-ion conductivity arises from the formation of a significant density of glass/ceramic interfaces, enabling percolation of interfacial or amorphous pathways.

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