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Pengyan Wu, Jian Wang, Cheng He, Xiaolin Zhang, Yanting Wang, Tao Liu and Chunying Duan Luminescent Metal-Organic Frameworks for Selectively Sensing Nitric Oxide in an Aqueous Solution and in Living Cells Advanced Functional Materials 22

Version of Record online: 6 FEB 2012 | DOI: 10.1002/adfm.201102157

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A new metal-organic framework (MOF)-based luminescence NO chemosensor with triphenylamine blue emitters is consolidated by the well-established Cu2(O2CR)4 paddlewheel units and successfully applied in luminescene detection of NO in aqueous solution and bioimaging of NO in living cells. The quenched triphenylamine-based emission is recovered upon encapsulating NO directly. The sensor exhibits excellent selectivity for NO over other reactive species in biological systems.

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