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Brett D. Martin, Gusphyl A. Justin, Martin H. Moore, Jawad Naciri, Theresa Mazure, Brian J. Melde, Rhonda M. Stroud and Banahalli Ratna An Elastomeric Poly(Thiophene-EDOT) Composite with a Dynamically Variable Permeability Towards Organic and Water Vapors Advanced Functional Materials 22

Version of Record online: 24 APR 2012 | DOI: 10.1002/adfm.201102237

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An interpenetrating polymer network (IPN) with molecular tethers can be reversibly switched between two conducting states by the application of a small voltage in the absence of standard liquid electrolyte. The switching causes the nanoporosity of the IPN to change, thus the IPN is able to adopt an “open” state and a “closed” state. The diffusivities of vapor molecules are strongly influenced by the changes in nanoporosity.

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