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Junying Liu, Dahlia Haynes, Courtney Balliet, Rui Zhang, Tomasz Kowalewski and Richard D. McCullough Self Encapsulated Poly(3-hexylthiophene)-poly(fluorinated alkyl methacrylate) Rod-Coil Block Copolymers with High Field Effect Mobilities on Bare SiO2 Advanced Functional Materials 22

Article first published online: 16 JAN 2012 | DOI: 10.1002/adfm.201102431

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The attachment of a semifluorinated block can significantly improve upon the charge carrier properties of regioregular poly(3-hexyl thiophene) (P3HT) on bare SiO2. The mobilities of poly(3-hexyl thiophene)-block-polyfluoromethacry-lates can approach up to 0.12 cm2 V−1 s−1 with only 33 wt% of the P3HT block incorporated in the copolymer.

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