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Yi Lu, Jiang-Ping Tu, Qin-Qin Xiong, Jia-Yuan Xiang, Yong-Jin Mai, Jun Zhang, Yan-Qiang Qiao, Xiu-Li Wang, Chang-Dong Gu and Scott X. Mao Controllable Synthesis of a Monophase Nickel Phosphide/Carbon (Ni5P4/C) Composite Electrode via Wet-Chemistry and a Solid-State Reaction for the Anode in Lithium Secondary Batteries Advanced Functional Materials 22

Version of Record online: 24 MAY 2012 | DOI: 10.1002/adfm.201102660

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Monophase nickel phosphide/carbon (Ni5P4/C) composites are controllably synthesized via a two-step reaction: a wet-chemistry reaction and a solid-state reaction. Highly crystalline Ni5P4/C spheres with uniform morphology are obtained. The composites exhibit a high specific capacity and rate performance, as well as good cyclic stability, making them one of the most promising anode materials for lithium-ion batteries.

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