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Jason L. Goldman, Brandon R. Long, Andrew A. Gewirth and Ralph G. Nuzzo LITHIUM-ION BATTERIES: Strain Anisotropies and Self-Limiting Capacities in Single-Crystalline 3D Silicon Microstructures: Models for High Energy Density Lithium-Ion Battery Anodes (Adv. Funct. Mater. 13/2011) Advanced Functional Materials 21

Version of Record online: 1 JUL 2011 | DOI: 10.1002/adfm.201190051

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This false-colored SEM image shows a model high-energy- density lithium-ion battery anode that consists of an array of 3D hierarchically patterned single-crystalline silicon microstructures. Ralph G. Nuzzo and co-workers utilize these model anodes to demonstrate the crystallographic anisotropy of strain evolution on electrochemical intercalation of lithium atoms and self-strain-limited charging of a lithium-ion battery anode.

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