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Toribio F. Otero and Jose G. Martinez Structural and Biomimetic Chemical Kinetics: Kinetic Magnitudes Include Structural Information Advanced Functional Materials 23

Article first published online: 10 SEP 2012 | DOI: 10.1002/adfm.201200719

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Reaction coefficients, activation energies, and reaction orders for a reaction change are reported for different packed conformational structures selected as the initial state. The kinetic magnitudes include quantitative information about the structural conformational state of the chains and the chemical kinetics become structural chemical kinetics. The results are described using the electrochemically stimulated conformational relaxation (ESCR) model.

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