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Manda Xiao, Chunmei Zhao, Huanjun Chen, Baocheng Yang and Jianfang Wang “Ship-in-a-Bottle” Growth of Noble Metal Nanostructures Advanced Functional Materials 22

Version of Record online: 29 JUN 2012 | DOI: 10.1002/adfm.201200941

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Different monometallic Au and bimetallic Au-cored nanostructures are grown using a “ship-in-a-bottle” technique in hollow mesoporous silica microspheres. The microsphere-encapsulated Au nanorod core/Pt shell nanostructures exhibit both high catalytic performance and superior recyclability in the oxidation reaction of o-phenylenediamine with hydrogen peroxide, while the conversion percentage in the presence of the corresponding unencapsulated nanostructures decreases rapidly with the recycle number.

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