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Kashinath A. Bogle, Jeffrey Cheung, Yong-Lun Chen, Sheng-Chieh Liao, Chih-Hung Lai, Ying-Hao Chu, John M. Gregg, Satishchandra B. Ogale and Nagarajan Valanoor Epitaxial Magnetic Oxide Nanocrystals Via Phase Decomposition of Bismuth Perovskite Precursors Advanced Functional Materials 22

Article first published online: 31 JUL 2012 | DOI: 10.1002/adfm.201201066

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Ferromagnetic oxides (M-Ox, with M = Mn, Fe, Co, and Cr) nanocrystal arrays are synthesized using a template-free facile approach through decomposition of a pulsed laser deposited bismuth metal oxide (BiMO3) precursor. This decomposition produces bismuth oxide (Bi2O3) and metal oxide (M-Ox) pockets. The subsequent cooling in vacuum volatizes the Bi2O3 leaving an array of monodisperse nanocrystals.

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