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Nayool Shin, Jihoon Kang, Lee J. Richter, Vivek M. Prabhu, R. Joseph Kline, Daniel A. Fischer, Dean M. DeLongchamp, Michael F. Toney, Sushil K. Satija, David J. Gundlach, Balaji Purushothaman, John E. Anthony and Do Y. Yoon Vertically Segregated Structure and Properties of Small Molecule–Polymer Blend Semiconductors for Organic Thin-Film Transistors Advanced Functional Materials 23

Version of Record online: 27 AUG 2012 | DOI: 10.1002/adfm.201201389

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Vertical phase segregation in blend films of an organic small molecule semiconductor, diF-TESADT, and various binder polymers are investigated. Comprehensive structural analysis reveals that the choice of polymer can strongly affect the structure of blend films due to the competing effects of confinement entropy, interaction energy, and solidification kinetics.

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