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Peter M. Marley, Adam A. Stabile, Chun Pui Kwan, Sujay Singh, Peihong Zhang, G. Sambandamurthy and Sarbajit Banerjee Charge Disproportionation and Voltage-Induced Metal–Insulator Transitions Evidenced in β-PbxV2O5 Nanowires Advanced Functional Materials 23

Article first published online: 17 AUG 2012 | DOI: 10.1002/adfm.201201513

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A synthetic route to nanowires of β-PbxV2O5 and evidence of an unprecedented voltage-induced metal–insulator transition in these materials is presented. X-ray diffraction and X-ray absorption spectroscopy experiments are consistent with charge ordering and electronic structure calculations suggest the appearance of a mid-gap state.

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