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Johannes Ihli, Yi-Yeoun Kim, Elizabeth H. Noel and Fiona C. Meldrum The Effect of Additives on Amorphous Calcium Carbonate (ACC): Janus Behavior in Solution and the Solid State Advanced Functional Materials 23

Article first published online: 19 OCT 2012 | DOI: 10.1002/adfm.201201805

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Investigation of the crystallization, in solution and in the solid state, of amorphous calcium carbonate (ACC) samples, precipitated in the presence of contrasting additives shows that high-molecular-weight additives can retard the crystallization of ACC in solution, yet accelerate this process in the solid state. In contrast, the small molecules studied retard crystallization in both solution and the solid state.

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