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Juliana Isabel Clodt, Volkan Filiz, Sofia Rangou, Kristian Buhr, Clarissa Abetz, Daniel Höche, Janina Hahn, Adina Jung and Volker Abetz Double Stimuli-Responsive Isoporous Membranes via Post-Modification of pH-Sensitive Self-Assembled Diblock Copolymer Membranes Advanced Functional Materials 23

Article first published online: 18 SEP 2012 | DOI: 10.1002/adfm.201202015

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Double stimuli-responsive membranes are prepared by modification of pH-sensitive integral asymmetric polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymer membranes with temperature-responsive poly(N-isopropylacrylamide) (pNIPAM). PS-b-P4VP membranes are first functionalized with a mussel-inspired polydopamine coating and then reacted with amine-terminated pNIPAM. The pH- and thermo-double sensitivities of the modified membranes are proven by determining the water flux under different temperature and pH conditions.

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