Venkata Bharat Ram Boppana, Seif Yusuf, Gregory S. Hutchings and Feng Jiao Nanostructured Alkaline-Cation-Containing δ-MnO2 for Photocatalytic Water Oxidation Advanced Functional Materials 23
Alkaline-cation-containing δ-MnO2 nanosheets and nanoparticles are fabricated, and both exhibit a high catalytic activity in visible-light-driven water oxidation. The alkaline-cation-containing δ-MnO2 exhibit activities per surface site approximately one order magnitude higher than a H-δ-MnO2 catalyst with a similar morphology and crystal structure. The alkaline cations are not directly involved in the catalytic water oxidation, but stabilize the MnO2 layers.
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