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Mi Liu, Pasquale Tirino, Milos Radivojevic, Daniel J. Phillips, Matthew I. Gibson, Jean-Christophe Leroux and Marc A. Gauthier Molecular Sieving on the Surface of a Protein Provides Protection Without Loss of Activity Advanced Functional Materials 23

Article first published online: 15 NOV 2012 | DOI: 10.1002/adfm.201202227

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Protein-bound monolayers of poly(oligoethyleneglycol monomethylether methacrylate) (pOEGMA) display selective permeability or “molecular sieving” characteristics when in the correct conformation/packing regime. The first conformational/permeability diagram of protein-bound pOEGMA mono layers is presented and insight for the design of therapeutic bioconjugates and functional coatings with selective permeability properties is provided.

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