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Jesse R. Manders, Sai-Wing Tsang, Michael J. Hartel, Tzung-Han Lai, Song Chen, Chad M. Amb, John R. Reynolds and Franky So Solution-Processed Nickel Oxide Hole Transport Layers in High Efficiency Polymer Photovoltaic Cells Advanced Functional Materials 23

Version of Record online: 16 JAN 2013 | DOI: 10.1002/adfm.201202269

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By replacing poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole-transporting layers (HTLs) with solution-processed nickel oxide (NiO), polymer photovoltaic cells with a power conversion efficiency of 7.8% are fabricated. Solar cells with NiO are more efficient and more air stable than those with PEDOT:PSS. The HTL/active layer interface plays a critical role in solar cell performance.

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