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Andreas A. Reitinger, Naima A. Hutter, Andreas Donner, Marin Steenackers, Oliver A. Williams, Martin Stutzmann, Rainer Jordan and Jose A. Garrido Functional Polymer Brushes on Diamond as a Platform for Immobilization and Electrical Wiring of Biomolecules Advanced Functional Materials 23

Version of Record online: 16 JAN 2013 | DOI: 10.1002/adfm.201202342

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Polymer brushes created by self-initiated photografting and photopolymerization provide a straightforward route for the biofunctionalization of bioelectronic devices, where a high loading and stable immobilization of biomolecules as well as a biocompatible environment and efficient charge transfer are essential. The potential of this approach is demonstrated by the example of amperometric glucose sensing with glucose oxidase- and ferrocene-functionalized poly(methacrylic acid) brushes on nanocrystalline diamond electrodes.

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