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Paul S. Campbell, Chantal Lorbeer, Joanna Cybinska and Anja-Verena Mudring One-Pot Synthesis of Luminescent Polymer-Nanoparticle Composites from Task-Specific Ionic Liquids Advanced Functional Materials 23

Version of Record online: 31 JAN 2013 | DOI: 10.1002/adfm.201202472

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A multifunction polymerizable ionic liquid, diallyldimethylammonium tetrafluoroborate, is used in a one-pot synthesis of novel luminescent polymer-nanoparticle composites. Small monodisperse lanthanide fluoride nanoparticles are formed by microwave irradiation in the presence of Ln(OAc)3·xH2O (Ln = Gd, Eu, Tb, OAc = acetate) in the ionic liquid. Irradiation under high intensity UV gives colorless, processable polymer materials with good photophysical properties.

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