L. Qiao, K. H. L. Zhang, M. E. Bowden, T. Varga, V. Shutthanandan, R. Colby, Y. Du, B. Kabius, P. V. Sushko, M. D. Biegalski and S. A. Chambers The Impacts of Cation Stoichiometry and Substrate Surface Quality on Nucleation, Structure, Defect Formation, and Intermixing in Complex Oxide Heteroepitaxy–LaCrO3 on SrTiO3(001) Advanced Functional Materials 23
The effect of cation stoichiometry and substrate defect density on nucleation, structure, defect formation, and interfacial mixing during III-III perovskite complex oxide heteroepitaxy is explored. Cation imbalance is shown to result in anti-site defect formation within the film, and subsurface cation vacancies promote cation mixing.
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