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David S. Liu, J. Nathan Ashcraft, Matthew M. Mannarino, Meredith N. Silberstein, Avni A. Argun, Gregory C. Rutledge, Mary C. Boyce and Paula T. Hammond Spray Layer-by-Layer Electrospun Composite Proton Exchange Membranes Advanced Functional Materials 23

Version of Record online: 18 JAN 2013 | DOI: 10.1002/adfm.201202892

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Polymer electrolyte films are deposited onto highly porous electrospun mats using layer-by-layer (LbL) processing to fabricate composite proton conducting membranes. Various dip and spray processing techniques are investigated for different and unique composite film morphologies. By combining the different spray-LbL fabrication techniques with electrospun fiber supports and tuning the parameters, mechanically stable membranes with high selectivity can be produced.

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