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Yuxin Tang, Zhelong Jiang, Guichuan Xing, Anran Li, Pushkar D. Kanhere, Yanyan Zhang, Tze Chien Sum, Shuzhou Li, Xiaodong Chen, Zhili Dong and Zhong Chen Efficient Ag@AgCl Cubic Cage Photocatalysts Profit from Ultrafast Plasmon-Induced Electron Transfer Processes Advanced Functional Materials 23

Article first published online: 23 JAN 2013 | DOI: 10.1002/adfm.201203379

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A novel and economic water-soluble sacrificial salt-crystal-template process is developed for the large-scale production of hollow Ag@AgCl cage materials. The hollow Ag@AgCl cages show superior photocatalytic performance (28 times larger) compared with the solid form, which profits from the highly efficient electron-hole pair separation that results from ultrafast plasmon-induced electron transfer from Ag nanoparticles to the AgCl surface.

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