Young-Si Jun, Eun Zoo Lee, Xinchen Wang, Won Hi Hong, Galen D. Stucky and Arne Thomas From Melamine-Cyanuric Acid Supramolecular Aggregates to Carbon Nitride Hollow Spheres Advanced Functional Materials 23
Simple molecular engineering of triazine precursors enables simultaneous optimization of the texture and photoelectric properties of graphitic carbon nitride (g-CN). Thermolysis of flower-like supramolecular aggregates of melamine and cyanuric acid yields the formation of mesoporous g-CN hollow spheres with the typical nanosheet-type structure preserved in the microspheres. Such structures are highly active in the photocatalytic degradation of organic pollutants.
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